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JEE Mains · Chemistry · STD 12 - 8.2 Carboxylic acids and their derivative

अम्ल प्रबलता के लिए सही घटता क्रम है:

  1. A \(NO_2CH_2COOH > FCH_2COOH >\) \( CNCH_2COOH > ClCH_2COOH\)
  2. B  \(FCH_2COOH > NCCH_2COOH >\)  \(NO_2CH_2COOH > ClCH_2COOH\)
  3. C \(CNCH_2COOH > O_2NCH_2COOH >\)  \(FCH_2COOH > ClCH_2COOH\)
  4. D \(NO_2CH_2COOH > NCCH_2COOH >\)  \(FCH_2COOH > ClCH_2COOH\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(NO_2CH_2COOH > NCCH_2COOH >\)  \(FCH_2COOH > ClCH_2COOH\)

Step-by-step Solution

Detailed explanation

Acid strength in this case varies directly with the electron withdrawing power of the groups attached to the \(\alpha - \) carbon of \(CH_3COOH\). The order of electron withdrawing tendency is \(NO_2 > CN > F > Cl\)
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