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WBJEE · Chemistry · Solutions

At a certain temperature, the value of the slope of the plot of osmotic pressure \((\pi)\) against concentration \(\left(C\right.\) in \(\mathrm{mol} \mathrm{L}^{-1}\) ) of a certain polymer solution is \(291 \mathrm{R.}\) The temperature at which osmotic pressure is measured, is \((R\) is gas constant)

  1. A \(271 ^\circ \mathrm{C}\)
  2. B \(18 ^\circ \mathrm{C}\)
  3. C \(564 \mathrm{k}\)
  4. D \(18 \mathrm{K}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(18 ^\circ \mathrm{C}\)

Step-by-step Solution

Detailed explanation

\[ \begin{array}{l} \text { Slope. } R T=291 R \text { or } T=291 \mathrm{K} \\ \therefore \text { Temperature }=291-273=18^{\circ} \mathrm{C} \end{array} \]