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WBJEE · Chemistry · Thermodynamics (C)

A plot of In \(\mathrm{k}\) against \(\frac{1}{\mathrm{~T}}\) (abscissa) is expected to be a straight line with intercept on ordinate axis equal to

  1. A \(\frac{\Delta \mathrm{S}^{\circ}}{2.303 \mathrm{R}}\)
  2. B \(\frac{\Delta \mathrm{S}^{\circ}}{\mathrm{R}}\)
  3. C \(-\frac{\Delta S^{\circ}}{R}\)
  4. D \(\mathrm{R} \times \Delta \mathrm{S}^{\circ}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(\frac{\Delta \mathrm{S}^{\circ}}{\mathrm{R}}\)

Step-by-step Solution

Detailed explanation

Hints: \(\Delta \mathrm{G}^{\circ}=-\mathrm{RT} \operatorname{InK}\) or, \(\Delta \mathrm{H}^{\circ}-\mathrm{T} \Delta \mathrm{S}^{\circ}=-\mathrm{RT} \operatorname{InK}\) or,…