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WBJEE · Chemistry · Thermodynamics (C)

For the reaction. \(X_{2} Y_{4}(I) \rightarrow 2 X Y_{2}(g)\) at \(300 \mathrm{K}\), the values of \(\Delta U\) and \(\Delta\) S are \(2 \mathrm{kcal}\) and 20 cal \(\mathrm{K}^{-1}\) respectively. The value of \(\Delta G\) for the reaction is

  1. A -3400 cal
  2. B 3400 cai
  3. C \(-2800 \mathrm{cal}\)
  4. D 2000 cal
Verified Solution

Answer & Solution

Correct Answer

(C) \(-2800 \mathrm{cal}\)

Step-by-step Solution

Detailed explanation

For the reaction \(X_{2} Y_{4}(I) \longrightarrow 2 X Y_{2}(g)\) \(\Delta n_{g}=\) number of gaseous products - number of gaseous reactants \[ \Delta n_{g}=2-0=2 \] Given that, \(\Delta U=2\) kcal \[ \Delta S=20 \text { cal } K^{-1} \] From the formula,…