TS EAMCET · Chemistry · Hydrocarbons
Which one of the following has highest boiling point?
- A \(\mathrm{H}_3 \mathrm{CCH}_2 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{Cl}\)
- B \(\left(\mathrm{H}_3 \mathrm{C}\right)_2 \mathrm{CHCH}{ }_2 \mathrm{Cl}\)
- C \[ \text { }\left(\mathrm{H}_3 \mathrm{C}\right)_3 \mathrm{CCl} \]
Answer & Solution
Correct Answer
(A) \(\mathrm{H}_3 \mathrm{CCH}_2 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{Cl}\)
Step-by-step Solution
Detailed explanation
\(\mathrm{H}_3 \mathrm{CCH}_2 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{Cl}\) For isomeric alkyl halides, the boiling points decreases with branching. Branching of the chain makes the molecule more compact and therefore, the surface area decreases. Hence, the intermolecular attractive…
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