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TS EAMCET · Chemistry · Alcohols Phenols and Ethers

Which one among the following reaction products gives iodoform test?

  1. A CH3CH2CH2C=N(ii)H3O+(i)C6H5MgBr
  2. B C6H52CdCH3COCl
  3. C CH2=CHCH2CHOHC6H5PCC
  4. D C6H5CH2CN(ii)H3O+(i)C2H3MgBr
Verified Solution

Answer & Solution

Correct Answer

(B) C6H52CdCH3COCl

Step-by-step Solution

Detailed explanation

The compounds which give positive are the one with alpha-methyl groups. To be more precise, Ethanal(Acetaldehyde) and methyl ketones. Ethanal is the only aldehyde which gives a positive iodoform test. The reagent I2+NaOH or NaOI are used in iodoform test. Acetaldehyde,all methyl…