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TS EAMCET · Chemistry · Polymers

Which of the following vinyl derivatives is the most reactive towards anionic polymerisation?

  1. A \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{CH}_2-\mathrm{CH}_3\)
  2. B \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{CH}_2-\mathrm{OE}\)
  3. C \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{Cl}\)
  4. D \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{C} \equiv \mathrm{N}\)
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Correct Answer

(D) \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{C} \equiv \mathrm{N}\)

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Anionic polymerisation can anionic initiator generates a carbanionic intermediate and such polymerisation is termed anionic addition polymerisation. In this case, the active centre of propagating species has negative charge. So, it takes place easily with the monomer having…
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