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TS EAMCET · Chemistry · Thermodynamics (C)

The standard enthalpy of combustion of C (graphite), \(\mathrm{H}_2\) (g) and \(\mathrm{CH}_3 \mathrm{OH}(l)\) respectively are \(-393,-286\) and -726 \(\mathrm{kJ} \mathrm{mol}^{-1}\). What is the standard enthalpy of formation of methanol?

  1. A \(-726 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
  2. B \(-239 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
  3. C \(-96 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
  4. D \(+96 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(-239 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

Step-by-step Solution

Detailed explanation

\begin{array}{l} \mathrm{C}+\mathrm{O}_2 \rightarrow, \mathrm{CO}_2 \Delta \mathrm{H}=-393 \mathrm{~kJ} \mathrm{~mol}^{-1} \\2 \mathrm{H}_2+\mathrm{O}_2 \rightarrow 2 \mathrm{H}_2 \mathrm{O}, \Delta \mathrm{H}=-2 \times 286=-572 \mathrm{~kJ} \mathrm{~mol}^{-1} \\\mathrm{CO}_2+2…