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TS EAMCET · Chemistry · Coordination Compounds

Which compound is zero valent metal complex?

  1. A \(\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right] \mathrm{SO}_4\)
  2. B \(\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]\)
  3. C \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\)
  4. D \(\mathrm{K}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]\)
Verified Solution

Answer & Solution

Correct Answer

(C) \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\)

Step-by-step Solution

Detailed explanation

\(\left[\stackrel{0}{\mathrm{Ni}}(\mathrm{CO})_4\right] \Rightarrow \mathrm{CO}\) is a neutral ligand. So, in metal carbonyls metal is present in their zero valent state.