KCET · Chemistry · Surface Chemistry

For the coagulations of positively charged hydrated ferric - oxide sol, the flocculating power of the ions is in the order:

A \(\mathrm{PO}_4^{3-}\gt\mathrm{SO}_4^{2-}\gt\mathrm{Cl}^{-}\gt\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}\)
B \(\mathrm{Cl}^{-}\gt\mathrm{SO}_4^{2-}\gt\mathrm{PO}_4^{3-}\gt\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}\)
C \(\mathrm{SO}_4^{2-}=\mathrm{Cl}^{-}=\mathrm{PO}_4^{3-}=\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}\)
D \(\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}\gt\mathrm{PO}_4^{3-}\gt\mathrm{SO}_4^{2-}\gt\mathrm{Cl}^{-}\)

Verified Solution

Answer & Solution

Correct Answer

(D) \(\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}\gt\mathrm{PO}_4^{3-}\gt\mathrm{SO}_4^{2-}\gt\mathrm{Cl}^{-}\)

Step-by-step Solution

Detailed explanation

Generally, greater the valence of the flocculating ion added, the greater is its power to cause precipitation. This is called as Hardy-Schulze rule.
So according to Hardy-Schulze rule the flocculating power of the ions is in the order \(\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}\gt\mathrm{PO}_4^{3-}\gt\mathrm{SO}_4^{2-}\gt\mathrm{Cl}^{-}\)

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Explore more questions on app

From KCET

Explore more questions on app