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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

Which of the following \(3 d -m e t a l\) ion will give the lowest enthalpy of hydration \((\Delta_{ hyd } H )\) when dissolved in water?

  1. A \(Cr ^{2+}\)
  2. B \(Mn ^{2+}\)
  3. C \(Fe ^{2+}\)
  4. D \(Co ^{2+}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(Mn ^{2+}\)

Step-by-step Solution

Detailed explanation

Enthalpy of hydration increases with increase in charge density. \(Mn ^{+2}\) has least charge density (as \(Mn\) has highest size among the given options) so it will have least enthalpy of hydration.
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