JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
Number of paramagnetic complexes among the following is ________.
\([\text{MnBr}_4]^{2-}\), \([\text{NiCl}_4]^{2-}\), \([\text{Ni(CN)}_4]^{2-}\), \([\text{Ni(CO)}_4]\), \([\text{CoF}_6]^{3-}\), \([\text{Fe(CN)}_6]^{4-}\), \([\text{Mn(CN)}_6]^{3-}\), \([\text{Ti(CN)}_6]^{3-}\), \([\text{Cu(H}_2\text{O)}_6]^{2+}\), \([\text{Co(C}_2\text{O}_4\text{)}_3]^{3-}\)
- A 6
- B 12
- C 24
- D 48
Answer & Solution
Correct Answer
(A) 6
Step-by-step Solution
Detailed explanation
To determine the magnetic nature of the given complexes, we analyze the oxidation state, electronic configuration, and the nature of the ligands for each central metal atom/ion: 1. \([\text{MnBr}_4]^{2-}\): Mn\(^{2+}\) has a \(3d^5\) configuration. Br\(^-\) is a weak field…
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