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JEE Advanced · Physics · 27. Atomic Physics

The largest wavelength in the ultraviolet region of the hydrogen spectrum is \(122 \mathrm{~nm}\). The smallest wavelength in the infrared region of the hydrogen spectrum (to the nearest integer) is

  1. A \(802 \mathrm{~nm}\)
  2. B \(823 \mathrm{~nm}\)
  3. C \(1882 \mathrm{~nm}\)
  4. D \(1648 \mathrm{~nm}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(823 \mathrm{~nm}\)

Step-by-step Solution

Detailed explanation

The series in \(U-V\) region is Lymen series. Longest wavelength corresponds to minimum energy which occurs in transition from \(n=2\) to \(n=1\).
\(
\therefore 122=\frac{\frac{1}{R}}{\left(\frac{1}{1^2}-\frac{1}{2^2}\right)}
\)
The smallest wavelength in the infrared region corresponds to maximum energy of Paschen series.
\(
\lambda=\frac{\frac{1}{R}}{\left(\frac{1}{3^2}-\frac{1}{\infty}\right)}
\)
Solving Eqs. (i) and (ii), we get
\(\therefore\) Correct option is (b).
\(
\lambda=823.5 \mathrm{~nm}
\)
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