The figure below is the plot of potential energy versus internuclear distance $\left(\mathrm{d}\right)$ of ${\mathrm{H}}_2$ molecule in the electronic ground state. What is the value of the net potential energy ${\mathrm{E}}_0$ (as indicated in the figure) in $\mathrm{kJ}{\mathrm{mol}}^{-1},$ for $\mathrm{d}={\mathrm{d}}_0$ at which the electron-electron repulsion and the nucleus-nucleus repulsion energies are absent? As reference, the potential energy of $\mathrm{H}$ atom is taken as zero when its electron and the nucleus are infinitely far apart.
Use Avogadro constant as $6.023\times {10}^{23}{\mathrm{mol}}^{-1}.$

Mark total potential energy for 2 H-atom (per mole) as answer.

Consider the reaction $\mathrm{A}\rightleftharpoons \mathrm{B}$ at $1000\mathrm{K}$. At time ${\mathrm{t}}^{\text{'}}$, the temperature of the system was increased to $2000\mathrm{K}$ and the system was allowed to reach equilibrium. Throughout this experiment the partial pressure of $\mathrm{A}$ was maintained at $1$ bar. Given below is the plot of the partial pressure of $\mathrm{B}$ with time. What is the ratio of the standard Gibbs energy of the reaction at $1000\mathrm{K}$ to that at $2000\mathrm{K}$?

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Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately \(6.023 \times 10^{23}\) ) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following example illustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.
A \(4.0\) molar aqueous solution of \(\mathrm{NaCl}\) is prepared and \(500 \mathrm{~mL}\) of this solution is electrolysed. This leads to the evolution of chlorine gas at one of electrodes (atomic mass: \(\mathrm{Na}=23, \mathrm{Hg}=200 ; 1\) faraday \(=96500\) coulombs).
Question:
If the cathode is a Hg electrode, the maximum weight \((g)\) of amalgam formed from this solution is

For the first order reaction \(2 \mathrm{~N}_2 \mathrm{O}_5(\mathrm{~g}) \longrightarrow 4 \mathrm{NO}_2(g)+\mathrm{O}_2(g)\)

If the reaction sequence given below is carried out with $15$ moles of acetylene, the amount of the product $\mathrm{D}$ formed (in $\mathrm{g}$) is The yields of $\mathrm{A},\mathrm{B},\mathrm{C}$ and $\mathrm{D}$ are given in parentheses. [Given: Atomic mass of $\mathrm{H}=1,\mathrm{C}=12,\mathrm{O}=16,\mathrm{Cl}=35$]

In the following monobromination reaction, the number of possible chiral products is

A sample \((5.6 \mathrm{~g})\) containing iron is completely dissolved in cold dilute \(\mathrm{HCl}\) to prepare a \(250 \mathrm{~mL}\) of solution. Titration of \(25.0 \mathrm{~mL}\) of this solution requires \(12.5 \mathrm{~mL}\) of \(0.03 \mathrm{M} \mathrm{KMnO}_{4}\) solution to reach the end point. Number of moles of \(\mathrm{Fe}^{2+}\) present in \(250 \mathrm{~mL}\) solution is \(\mathbf{x} \times 10^{-2}\) (consider complete dissolution of \(\mathrm{FeCl}_{2}\) ). The amount of iron present in the sample is \(\mathbf{y} \%\) by weight.
(Assume: \(\mathrm{KMnO}_{4}\) reacts only with \(\mathrm{Fe}^{2+}\) in the solution Use: Molar mass of iron as \(56 \mathrm{~g} \mathrm{~mol}^{-1}\) )
The value of $\mathrm{y}$ is________ .

Three plane mirrors form an equilateral triangle with each side of length $L$. There is a small hole at a distance $l>0$ from one of the corners as shown in the figure. A ray of light is passed through the hole at an angle $\theta$ and can only come out through the same hole. The cross section of the mirror configuration and the ray of light lie on the same plane.

Which of the following statement(s) is(are) correct?

The circle $C_1:x^2+y^2=3,$ with centre at O, intersects the parabola $x^2=2y$ at the point P in the first quadrant. Let the tangent to the circle $C_1$ at P touches other two circles $C_2$ and $C_3$ at $R_2$ and $R_3$ , respectively. Suppose $C_2$ and $C_3$ have equal radii $2\sqrt{3}$ and centres $Q_2$ and ${ Q}_3$ , respectively. If $Q_2$ and $Q_3$ lie on the y - axis, then

The number of values of \(\theta\) in the interval \(\left(-\frac{\pi}{2}, \frac{\pi}{2}\right)\) such that \(\theta \neq \frac{n \pi}{5}\) for \(n=0, \pm 1, \pm 2\) and \(\tan \theta=\cot 5 \theta\) as well as \(\sin 2 \theta=\cos 4 \theta\) is

A person of height $1.6 \mathrm{m}$ is walking away from a lamp post of height $4 \mathrm{m}$ along a straight path on the flat ground. The lamp post and the person are always perpendicular to the ground. If the speed of the person is $60 \mathrm{cm} {\mathrm{s}}^{-1}$, the speed of the tip of the person’s shadow on the ground with respect to the person is _____ $\mathrm{cm} {\mathrm{s}}^{-1}$.

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Schemes \(1\) and \(2\) describe sequential transformation of alkynes \(\mathbf{M}\) and \(\mathbf{N}\). Consider only the major products formed in each step for both the schemes.



Question:
The correct statement with respect to product \(\mathbf{Y}\) is

If $M=\left(\begin{array}{cc}\frac{5}{2}& \frac{3}{2}\\ -\frac{3}{2}& -\frac{1}{2}\end{array}\right)$, then which of the following matrices is equal to $M^{2022}$ ?