A sample \((5.6 \mathrm{~g})\) containing iron is completely dissolved in cold dilute \(\mathrm{HCl}\) to prepare a \(250 \mathrm{~mL}\) of solution. Titration of \(25.0 \mathrm{~mL}\) of this solution requires \(12.5 \mathrm{~mL}\) of \(0.03 \mathrm{M} \mathrm{KMnO}_{4}\) solution to reach the end point. Number of moles of \(\mathrm{Fe}^{2+}\) present in \(250 \mathrm{~mL}\) solution is \(\mathbf{x} \times 10^{-2}\) (consider complete dissolution of \(\mathrm{FeCl}_{2}\) ). The amount of iron present in the sample is \(\mathbf{y} \%\) by weight.
(Assume: \(\mathrm{KMnO}_{4}\) reacts only with \(\mathrm{Fe}^{2+}\) in the solution Use: Molar mass of iron as \(56 \mathrm{~g} \mathrm{~mol}^{-1}\) )
The value of $\mathrm{y}$ is________ .

The diffusion coefficient of an ideal gas is proportional to its mean free path and mean speed. The absolute temperature of an ideal gas is increased $4$ times and its pressure $2$ times. As a result, the diffusion coefficient of this gas increases $\mathrm{x}$ times. The value of $\mathrm{x}$ is:

Hydrogen bonding plays a central role in the following phenomena:

For diatomic molecules, the correct statement(s) about the molecular orbitals formed by the overlap of two $2{\mathrm{p}}_{\mathrm{z}}$ orbitals is(are)

Among the following, intensive property is (properties are)

In the following monobromination reaction, the number of possible chiral products is

The product formed in the reaction of $\mathrm{S}\mathrm{O}\mathrm{C}{\mathrm{l}}_2$ with white phosphorous is

Let \(p(x)\) be a polynomial of degree 4 having extremum at \(x=1,2\) and \(\lim _{x \rightarrow 0}\left[1+\frac{p(x)}{x^2}\right]=2\). Then, the value of \(p(2)\) is

If \(f^{\prime \prime}(x)=-f(x)\), where \(f(x)\) is a continuous double differentiable function and \(g(x)=f^{\prime}(x)\). If \(F(x)=\left(f\left(\frac{x}{2}\right)\right)^2+\left(g\left(\frac{x}{2}\right)\right)^2\) and \(F(5)=5\), then \(F(10)\) is

One mole of an ideal gas at $900 \mathrm{K}$, undergoes two reversible processes, $\mathrm{I}$ followed by $\mathrm{II}$, as shown below. If the work done by the gas in the two processes are same, the value of $\ln \frac{{\mathrm{V}}_3}{{\mathrm{V}}_2}$ is ($\mathrm{U}$ : internal energy, $\mathrm{S}:$ entropy, $\mathrm{p}:$ pressure, $\mathrm{V}:$ volume, $\mathrm{R}$ : gas constant)  (Given: molar heat capacity at constant volume, ${\mathrm{C}}_{\mathrm{V},\mathrm{m}}$ of the gas is $\frac{5}{2}\mathrm{R}$)

Consider a system of three connected strings, \(S_1, S_2\) and \(S_3\) with uniform linear mass densities \(\mu \mathrm{kg} / \mathrm{m}\), \(4 \mu \mathrm{~kg} / \mathrm{m}\) and \(16 \mu \mathrm{~kg} / \mathrm{m}\), respectively, as shown in the figure. \(S_1\) and \(S_2\) are connected at the point \(P\), whereas \(S_2\) and \(S_3\) are connected at the point \(Q\), and the other end of \(S_3\) is connected to a wall. A wave generator O is connected to the free end of \(S_1\). The wave from the generator is represented by \(y=y_0\) \(\cos (\omega t-k x) \mathrm{cm}\), where \(y_0, \omega\) and \(k\) are constants of appropriate dimensions. Which of the following statements is/are correct:

Let \(S=\{1,2,3,4\}\). The total number of unordered pairs of disjoint subsets of \(S\) is equal to

Paragraph :
In the figure a container is shown to have a movable (without friction) piston on top. The container and the piston are all made of perfectly insulating material allowing no heat transfer between outside and inside the container. The container is divided into two compartments by a rigid partition made of a thermally conducting material that allows slow transfer of heat. The lower compartment of the container is filled with \(2\) moles of an ideal monatomic gas at \(700 K\) and the upper compartment is filled with \(2\) moles of an ideal diatomic gas at \(400 K\). The heat capacities per mole of an ideal monatomic gas are \(C_{V}=\frac{3}{2} R, C_{P}=\frac{5}{2} R\), and those for an ideal diatomic gas are \(C_{V}=\frac{5}{2} R, C_{P}=\frac{7}{2} R\).

Question :
Now consider the partition to be free to move without friction so that the pressure of gases in both compartments is the same. Then total work done by the gases till the time they achieve equilibrium will be