The correct match of the group reagents in List-I for precipitating the metal ion given in List-II from solutions, is

List - I	List - II
(P) Passing \(H _2 S\) in the presence of \(NH _4 OH\)	(1) \(Cu ^{2+}\)
(Q) \(\left( NH _4\right)_2 CO _3\) in the presence of \(NH _4 OH\)	(2) \(Al ^{3+}\)
(R) \(NH _4 OH\) in the presence of \(NH _4 Cl\)	(3) \(Mn ^{2+}\)
(S) Passing \(H _2 S\) in the presence of dilute HCl	(4) \(Ba ^{2+}\)
	(5) \(Mg ^{2+}\)

1. A \(\mathrm{P} \rightarrow 3 ; \mathrm{Q} \rightarrow 4 ; \mathrm{R} \rightarrow 2 ; \mathrm{S} \rightarrow 1\)
2. B \(\mathrm{P} \rightarrow 4 ; \mathrm{Q} \rightarrow 2 ; \mathrm{R} \rightarrow 3 ; \mathrm{S} \rightarrow 1\)
3. C \(\mathrm{P} \rightarrow 3 ; \mathrm{Q} \rightarrow 4 ; \mathrm{R} \rightarrow 1 ; \mathrm{S} \rightarrow 5\)
4. D \(\mathrm{P} \rightarrow 5 ; \mathrm{Q} \rightarrow 3 ; \mathrm{R} \rightarrow 2 ; \mathrm{S} \rightarrow 4\)