Statement I Glucose gives a reddish-brown precipitate with Fehling's solution.
Statement II Reaction of glucose with Fehling's solution gives \(\mathrm{CuO}\) and gluconic acid.

The stoichiometric reaction of $516 \mathrm{g}$ of dimethyldichlorosilane with water results in a tetrameric cyclic product $\mathbf{X}$ in $75\%$ yield. The weight (in $\mathrm{g}$) of $\mathbf{X}$ obtained is ____________
\(\left[\right.\)Use, molar mass\(.\left(\text{gmol} ^{-1}\right):\text H =1,\text C =12,\)\(\text O =16, \text{Si} =28, \text{Cl} =35.5]\)

Reagent(s) which can be used to bring about the following transformation is(are)

Paragraph:
Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately \(6.023 \times 10^{23}\) ) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following example illustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.
A \(4.0\) molar aqueous solution of \(\mathrm{NaCl}\) is prepared and \(500 \mathrm{~mL}\) of this solution is electrolysed. This leads to the evolution of chlorine gas at one of electrodes (atomic mass: \(\mathrm{Na}=23, \mathrm{Hg}=200 ; 1\) faraday \(=96500\) coulombs).
Question:
The total number of moles of chlorine gas evolved is

For the electrochemical cell, $\text{Mg(s)}\left|{\text{Mg}}^{\text{2+}}\left(\text{aq,1}\text{M}\right)\right|\left|{\text{Cu}}^{\text{2+}}\left(\text{aq,1}\text{M}\right)\right|\text{Cu }\left(\text{s}\right)$ the standard emf of the cell is $\text{2}\text{.70 V}$ at $\text{300 K}\text{.}$ When the concentration of ${\text{Mg}}^{\text{2+}}$ is changed to $\text{x M,}$ the cell potential changes to $\text{2}\text{.67 V}$ at $\text{300 K}\text{.}$ The value of $\text{x}$ is ________.
(given, $\frac{\text{F}}{\text{R}}{\text{=11500 K V}}^{-\text{1}}\text{,}$ where $\text{F}$ is the Faraday constant and $\text{R}$ is the gas constants, $\text{ln}\left(\text{10}\right)\text{=}\text{2}\text{.30}$ )

$2 \mathrm{mol}$ of $\mathrm{Hg}\left(\mathrm{g}\right)$ is combusted in a fixed volume bomb calorimeter with excess of ${\mathrm{O}}_2$ at $298 \mathrm{K}$ and $1 \mathrm{atm}$ into $\mathrm{HgO}\left(\mathrm{s}\right)$. During the reaction, temperature increases from $298.0 \mathrm{K}$ to $312.8 \mathrm{K}$. If heat capacity of the bomb calorimeter and enthalpy of formation of $\mathrm{Hg}\left(\mathrm{g}\right)$ are $20.00 \mathrm{kJ} {\mathrm{K}}^{-1}$ and $61.32 \mathrm{kJ} {\mathrm{mol}}^{-1}$ at $298 \mathrm{K}$, respectively, the calculated standard molar enthalpy of formation of $\mathrm{HgO}\left(\mathrm{s}\right)$ at $298 \mathrm{K}$ is $\mathrm{X} {\mathrm{kJmol}}^{-1}$. The value of $\left|\mathrm{X}\right|$ is___[Given: Gas constant $\mathrm{R}=8.3 \mathrm{J} {\mathrm{K}}^{-1} {\mathrm{mol}}^{-1}$]

Amongst the following, the total number of compounds soluble in aqueous \(\mathrm{NaOH}\) is

Paragraph:
The noble gases have closed-shell electronic configuration and are monoatomic gases under normal conditions. The low boiling points of the lighter noble gases are due to weak dispersion forces between the atoms and the absence of other interatomic interactions.
The direct reaction of xenon with fluorine leads to a series of compounds with oxidation numbers \(+2,+4\) and \(+6 . \mathrm{XeF}_4\) reacts violently with water to give \(\mathrm{XeO}_3\). The compounds of xenon exhibit rich stereochemistry and their geometries can be deduced considering the total number of electron pairs in the valence shell.
Question:
\(\mathrm{XeF}_4\) and \(\mathrm{XeF}_6\) are expected to be

A block of weight $100\mathrm{}\mathrm{N}$ is suspended by copper and steel wires of same cross-sectional area $0.5\mathrm{}\mathrm{c}{\mathrm{m}}^2$ and, length $\sqrt{3}\mathrm{}\mathrm{m}$ and $1\mathrm{}\mathrm{m},$ respectively. Their other ends are fixed on a ceiling as shown in figure. The angles subtended by copper and steel wires with ceiling are ${30}^{\mathrm{o}}$ and ${60}^{\mathrm{o}},$ respectively. If elongation in copper wire is $\left(\mathrm{\Delta }{\mathrm{l}}_{\mathrm{C}}\right)$ and elongation in steel wire is $\left(\mathrm{\Delta }{\mathrm{l}}_{\mathrm{S}}\right),$ then the ratio $\frac{\mathrm{\Delta }{\mathrm{l}}_{\mathrm{C}}}{\mathrm{\Delta }{\mathrm{l}}_{\mathrm{S}}}$ is _____.
[Young's modulus for copper and steel are $1\times {10}^{11}\mathrm{N}/{\mathrm{m}}^2$ and $2\times {10}^{11}\mathrm{N}/{\mathrm{m}}^2$ respectively]

Paragraph:

The figure shows a circular loop of radius \(a\) with two long parallel wires (numbered \(1\) and \(2\) ) all in the plane of the paper. The distance of each wire from the centre of the loop is \(d\). The loop and the wires are carrying the same current \(I\). The current in the loop is in the counterclockwise direction if seen from above.



Question:

When \(d \approx a\) but wires are not touching the loop, it is found that the net magnetic field on the axis of the loop is zero at a height \(h\) above the loop. In that case

Consider a star of mass \(m_2 \mathrm{~kg}\) revolving in a circular orbit around another star of mass \(m_1 \mathrm{~kg}\) with \(m_1 \gg m_2\). The heavier star slowly acquires mass from the lighter star at a constant rate of \(\gamma \mathrm{kg} / \mathrm{s}\). In this transfer process, there is no other loss of mass. If the separation between the centers of the stars is \(r\), then its relative rate of change \(\frac{1}{r} \frac{\mathrm{~d} r}{\mathrm{~d} t}\left(\right.\) in s \(\left.^{-1}\right)\) is given by:
[Note: The original question was awarded bonus marks in the JEE Advanced 2025 exam. We have changed the options to make the question valid and solvable.]

Paragraph :
A uniform thin cylindrical disk of mass \(M\) and radius \(R\) is attached to two identical massless springs of spring constant \(k\) which are fixed to the wall as shown in the figure. The springs are attached to the axle of the disk symmetrically on either side at a distance \(d\) from its centre. The axle is massless and both the springs and the axle are in a horizontal plane. The unstretched length of each spring is \(L\). The disk is initially at its equilibrium position with its centre of mass \((C M)\) at a distance Lfrom the wall. The disk rolls without slipping with velocity \(\mathbf{v}_0=v_0 \hat{\mathbf{i}}\) The coefficient of friction is \(\mu\).
Question :
The maximum value of \(v_0\) for which the disk will roll without slipping is

Three randomly chosen non negative integers $x,y,z$ are found to satisfy the equation  $x+y+z=10$ . Then the probability that $z$ is even, is