Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is (are)

A gas has a compressibility factor of $0.5$ and a molar volume of $0.4 {\mathrm{dm}}^3 {\mathrm{mol}}^{-1}$ at a temperature of $800 \mathrm{K}$ and pressure $\mathrm{x} \mathrm{atm}$. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be  $\mathrm{y} {\mathrm{dm}}^3 {\mathrm{mol}}^{-1}$ . The value of$\mathrm{x}/\mathrm{y}$ is _________
[Use: Gas constant, $\mathrm{R}=8\times {10}^{-2} \mathrm{L} \mathrm{atm} {\mathrm{K}}^{-1} {\mathrm{mol}}^{-1}$ ]

A gas described by van der Waals' equation

The number of geometric isomers possible for the complex ${\left[\text{C}\text{o}{\text{L}}_2\text{C}{\text{l}}_2\right]}^{-}\left(\text{L}={\text{H}}_2\text{N}\text{C}{\text{H}}_2\text{C}{\text{H}}_2{\text{O}}^{-}\right)$ is
 

Among the following, intensive property is (properties are)

Under ambient conditions, the total number of gases released as products in the final step of the reaction scheme shown below is

Statement \(\mathbf{1}\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{NO}\right] \mathrm{SO}_4\) is paramagnetic.
Statement 2 The \(\mathrm{Fe}\) in \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{NO}\right] \mathrm{SO}_4\) has three unpaired electrons.

Consider an obtuse angled triangle $ABC$ in which the difference between the largest and the smallest angle is $\frac{\pi }{2}$ and whose sides are in arithmetic progression. Suppose that the vertices of this triangle lie on a circle of radius $1$.

(There are two questions based on $\mathrm{PARAGRAPH} " 1 "$, the question given below is one of them)
Then the inradius of the triangle $ABC$ is

In a $∆PQR$, $P$ is the largest angle and $\cos P=\frac{1}{3}$. Further the incircle of the triangle touches the sides $PQ, QR$ and $RP$ at $N, L$ and $M$ respectively, such that the lengths of $PN, QL$ and $RM$ are consecutive even integers. Then possible length(s) of the side(s) of the triangle is (are)

A ball is thrown from the location \(\left(x_0, y_0\right)=(0,0)\) of a horizontal playground with an initial speed \(v_0\) at an angle \(\theta_0\) from the \(+x\)-direction. The ball is to be hit by a stone, which is thrown at the same time from the location \(\left(x_1, y_1\right)=(L, 0)\). The stone is thrown at an angle \(\left(180-\theta_1\right)\) from the \(+x\)-direction with a suitable initial speed. For a fixed \(v_0\), when \(\left(\theta_0, \theta_1\right)=\left(45^{\circ}, 45^{\circ}\right)\), the stone hits the ball after time \(T_1\), and when \(\left(\theta_0, \theta_1\right)=\left(60^{\circ}, 30^{\circ}\right)\), it hits the ball after time \(T_2\). In such a case, \(\left(T_1 / T_2\right)^2\) is _______ .

A thin rod of mass $M$ and length $a$ is free to rotate in horizontal plane about a fixed vertical axis passing through point $O$. A thin circular disc of mass $M$ and of radius $\frac{a}{4}$ is pivoted on this rod with its centre at a distance $\frac{a}{4}$ from the free end so that it can rotate freely about its vertical axis, as shown in the figure. Assume that both the rod and the disc have uniform density and they remain horizontal during the motion. An outside stationary conserver finds the rod rotating with an angular velocity $\Omega$ and the disc rotating about its vertical axis with angular velocity $4\Omega$. The total angular momentum of the system about the point $O$ is $\left[\left(\frac{M{a}^2\Omega }{48}\right)n\right]$. The value of $n$ is _________ .

Paragraph :
A special metal \(S\) conducts electricity without any resistance. A closed wire loop, made of \(S\), does not allow any change in flux through itself by inducing a suitable current to generate a compensating flux. The induced current in the loop cannot decay due to its zero resistance. This current gives rise to a magnetic moment which in turn repels the source of magnetic field or flux. Consider such a loop, of radius \(a\), with its center at the origin. A magnetic dipole of moment \(m\) is brought along the axis of this loop from infinity to a point at distance \(r(\gg a)\) from the center of the loop with its north pole always facing the loop, as shown in the figure below.

The magnitude of magnetic field of a dipole \(m\), at a point on its axis at distance \(r\), is \(\frac{\mu_{0}}{2 \pi} \frac{m}{r^{3}}\), where \(\mu_{0}\) is the permeability of free space. The magnitude of the force between two magnetic dipoles with moments, \(m_{1}\) and \(m_{2}\), separated by a distance \(r\) on the common axis, with their north poles facing each other, is \(\frac{k m_{1} m_{2}}{r^{4}}\), where \(k\) is a constant of appropriate dimensions. The direction of this force is along the line joining the two dipoles.

Question :
The work done in bringing the dipole from infinity to a distance$r$from the centre of the loop by the given process is proportional to:

For the reaction sequence given below, the correct statement(s) is(are)