The number of geometric isomers possible for the complex ${\left[\text{C}\text{o}{\text{L}}_2\text{C}{\text{l}}_2\right]}^{-}\left(\text{L}={\text{H}}_2\text{N}\text{C}{\text{H}}_2\text{C}{\text{H}}_2{\text{O}}^{-}\right)$ is
 

Among the following, the state function(s) is (are)

In the following monobromination reaction, the number of possible chiral products is

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Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately \(6.023 \times 10^{23}\) ) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following example illustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.
A \(4.0\) molar aqueous solution of \(\mathrm{NaCl}\) is prepared and \(500 \mathrm{~mL}\) of this solution is electrolysed. This leads to the evolution of chlorine gas at one of electrodes (atomic mass: \(\mathrm{Na}=23, \mathrm{Hg}=200 ; 1\) faraday \(=96500\) coulombs).
Question:
If the cathode is a Hg electrode, the maximum weight \((g)\) of amalgam formed from this solution is

The colour of the $X_2$ molecules of group 17 elements changes gradually from yellow to violet down the group. This is due to -

Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is

Paragraph I: An organic compound \(\mathbf{P}\) with molecular formula \(\mathrm{C}_9 \mathrm{H}_{18} \mathrm{O}_2\) decolorizes bromine water and also shows positive iodoform test. \(\mathbf{P}\) on ozonolysis followed by treatment with \(\mathrm{H}_2 \mathrm{O}_2\) gives \(\mathbf{Q}\) and \(\mathbf{R}\). While compound \(\mathbf{Q}\) shows positive iodoform test, compound \(\mathbf{R}\) does not give positive iodoform test. \(\mathbf{Q}\) and \(\mathbf{R}\) on oxidation with pyridinium chlorochromate (PCC) followed by heating give \(\mathbf{S}\) and \(\mathbf{T}\), respectively. Both \(\mathbf{S}\) and \(\mathbf{T}\) show positive iodoform test.
Complete copolymerization of 500 moles of \(\mathbf{Q}\) and 500 moles of \(\mathbf{R}\) gives one mole of a single acyclic copolymer \(\mathbf{U}\).
[Given, atomic mass: \(\mathrm{H}=1, \mathrm{C}=12, \mathrm{O}=16\)]
Question: Sum of number of oxygen atoms in \(\mathbf{S}\) and \(\mathbf{T}\) is

An optical component and an object \(S\) placed along its optic axis are given in Column I. The distance between the object and the component can be varied. The properties of images are given in Column II. Match all the properties of images from Column II with the appropriate components given in Column I. Indicate your answer by darkening the appropriate bubble of the \(4 \times 4\) matrix given in the ORS.

Let \(\gamma \in \mathbb{R}\) be such that the lines \(\mathrm{L}_1: \frac{x+11}{1}=\frac{\mathrm{y}+21}{2}=\frac{\mathrm{z}+29}{3}\) and \(L_2: \frac{x+16}{3}=\frac{y+11}{2}=\frac{z+4}{\gamma}\) intersect. Let \(\mathrm{R}_1\) be the point of intersection of \(\mathrm{L}_1\) and \(\mathrm{L}_2\). Let \(\mathrm{O}=(0,0,0)\), and \(\hat{\mathrm{n}}\) denote a unit normal vector to the plane containing both the lines \(\mathrm{L}_1\) and \(\mathrm{L}_2\).
Match each entry in List-I to the correct entry in List-II.

The correct option is

An annular disk of mass $M$, inner radius $a$ and outer radius $b$ is placed on a horizontal surface with coefficient of friction $\mu$, as shown in the figure. At some time, an impulse $J_0\stackrel{\wedge }{x}$ is applied at a height $h$ above the center of the disk. If $h=h_m$ then the disk rolls without slipping along the $x$-axis. Which of the following statement(s) is(are) correct?

Let $L_1$ and $L_2$ be the following straight lines.
$L_1:\frac{x-1}{1}=\frac{y}{-1}=\frac{z-1}{3}$ and $L_2:\frac{x-1}{-3}=\frac{y}{-1}=\frac{z-1}{1}$
Suppose the straight line $L:\frac{x-\alpha }{l}=\frac{y-1}{m}=\frac{z-\gamma }{-2}$ lies in the plane containing $L_1$ and $L_2$, and passes through the point of intersection of $L_1$ and $L_2$. If the line $L$ bisects the acute angle between the lines $L_1$ and $L_2$, then which of the following statements is/are TRUE?

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An aqueous solution of a mixture of two inorganic salts, when treated with dilute \(H C\) ?, gave a precipitate \((\boldsymbol{P})\) and a filtrate \((\boldsymbol{Q})\). The precipitate \(\boldsymbol{P}\) was found to dissolve in hot water. The filtrate \((\boldsymbol{Q})\) remained unchanged, when treated with \(\mathrm{H}_{2} \mathrm{~S}\) in a dilute mineral acid medium. However, it gave a precipitate \((\boldsymbol{R})\) with \(H_{2} S\) in an ammoniacal medium. The precipitate \(\boldsymbol{R}\) gave a coloured solution \((\boldsymbol{S})\), when treated with \(\mathrm{H}_{2} \mathrm{O}_{2}\) in an aqueous \(\mathrm{NaOH}\) medium.
Question:
The coloured solution \(\boldsymbol{S}\) contains

Two concentric circular loops, one of radius $R$ and the other of radius $2R$, lie in the $xy$-plane with the origin as their common center, as shown in the figure. The smaller loop carries current $I_1$ in the anti-clockwise direction and the larger loop carries current $I_2$ in the clockwise direction, with $I_2>2I_1. \overrightarrow{B}\left(x,y\right)$ denotes the magnetic field at a point $\left(x,y\right)$ in the $xy$-plane. Which of the following statement(s) is (are) correct?