Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the $n^{\mathrm{t}\mathrm{h}}$ orbit of the atom and List-II contains options showing how they depend on $n$ .
 

List - I	List - II
(I) Radius of the $n^{\mathrm{t}\mathrm{h}}$ orbit	$\left(\mathrm{P}\right)$ $\propto n^{-2}$
(II) Angular momentum of the electron in the $n^{th}$ orbit	$\left(\mathrm{Q}\right)$ $\propto n^{-1}$
(III) Kinetic energy of the electron in the $n^{\mathrm{t}\mathrm{h}}$ orbit	$\left(\mathrm{R}\right)$ $\propto n^0$
(IV) Potential energy of the electron in the $n^{\mathrm{t}\mathrm{h}}$ orbit	$\left(\mathrm{S}\right)$ $\propto n^1$
	$\left(\mathrm{T}\right)$ $\propto n^2$
	$\left(\mathrm{U}\right)$ $\propto n^{1/2}$

Which of the following options has the correct combination considering List-I and List-II?

Among the following, the correct statement(s) for electrons in an atom is(are)

Paragraph:

Thermal decomposition of gaseous \(\mathrm{X}_{2}\) to gaseous \(\mathrm{X}\) at \(298 \mathrm{~K}\) takes place according to the following equation:

\(\mathrm{X}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{X}(\mathrm{g})\)

The standard reaction Gibbs energy, \(\Delta_{r} G^{\circ}\), of this reaction is positive. At the start of the reaction, there is one mole of \(\mathrm{X}_{2}\) and no \(\mathrm{X}\). As the reaction proceeds, the number of moles of \(\mathrm{X}\) formed is given by \(\beta\). Thus, \(\beta_{\text {equilibrium }}\) is the number of moles of \(\mathrm{X}\) formed at equilibrium. The reaction is carried out at a constant total pressure of \(2\) bar. Consider the gases to behave ideally. (Given : \(R=0.083 \mathrm{~L}\) bar \(\mathrm{K}^{-1} \mathrm{~mol}^{-1}\) )

Question:
The equilibrium constant \(K_{P}\) for this reaction at \(298 \mathrm{~K},\) in terms of \(\beta_{equilibrium}\) is

With respect to the compounds$\mathrm{I}-\mathrm{V}$choose the correct statement(s).

$\mathrm{M}{\mathrm{X}}_2$ dissociates in ${\mathrm{M}}^{2+}$ and ${\mathrm{X}}^{-}$ ions in an aqueous solution, with a degree of dissociation $\left(\mathrm{\alpha }\right)$ of 0.5. The ratio of the observed depression of freezing point of the aqueous solution to the value of the depression of freezing point in the absence of ionic dissociation is

Paragraph:
Reimer-Tiemann reaction introduces an aldehyde group, on to the aromatic ring of phenol, ortho to the hydroxyl group. This reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of substituted salicylaldehydes as depicted below.

Question:
Which one of the following reagents is used the above reaction?

The heating of \(\mathrm{NH}_4 \mathrm{NO}_2\) at \(60-70^{\circ} \mathrm{C}\) and \(\mathrm{NH}_4 \mathrm{NO}_3\) at \(200-250^{\circ} \mathrm{C}\) is associated with the formation of nitrogen containing compounds \(\mathbf{X}\) and \(\mathbf{Y}\), respectively. \(\mathbf{X}\) and \(\mathbf{Y}\), respectively, are

An organic compound $\left({\mathrm{C}}_8{\mathrm{H}}_{10}{\mathrm{O}}_2\right)$ rotates plane-polarized light. It produces pink color with neutral ${\mathrm{FeCl}}_3$ solution. What is the total number of all the possible isomers for this compound?

The hyperconjugative stabilities of tert-butyl cation and 2-butene, respectively, due to 

Let $\overline{z}$ denote the complex conjugate of a complex number $z$ and let $i=\sqrt{-1}$. In the set of complex numbers, the number of distinct roots of the equation $\overline{z}-z^2=i\left(\overline{z}+z^2\right)$ is _______.

Let $F\mathbb{ }:\mathbb{ }\mathbb{R}\to \mathbb{R}$ be a thrice differentiable function. Suppose that $F\left(1\right)=0, F\left(3\right)= -4$ and $F\prime \left(x\right)<0$ all $x\in \left(\frac{1}{2}, 3\right).$ Let $f\left(x\right)=xF\left(x\right)$ for all $x\in \mathbb{ }\mathbb{R}$ .
If $\underset{1}{\overset{3}{\int }}{x}^2{F}^{\prime }\left(x\right)dx= -12$ and $\underset{1}{\overset{3}{\int }}{x}^3 F^{\prime \prime }\left(x\right)dx=40,$ then the correct expression(s) is(are)

Let \(z_1\) and \(z_2\) be two distinct complex numbers and let \(z=(1-t) z_1+t z_2\) for some real number \(t\) with \(0 < t < 1\). If \(\arg (w)\) denotes the principal argument of a non-zero complex number \(w\), then

The compound(s) with \(\mathrm{P}-\mathrm{H}\) bond(s) is(are)