Columns 1, 2 and 3 contain starting materials, reaction conditions and type of reactions respectively.

Column 1	Column 2	Column 3
(I) Toulene	(i) \(NaOH\) \( /Br _2\)	(P) Condensation
(II) Acetophenone	(ii) \(B r_2 / h v\)	(Q) Carboxylation
(III) Benzaldehyde	(iii) \(\left( CH _3 CO \right)_2\) \(O / CH _3\) \(COOK\)	(R) Substitution
(IV) Phenol	(iv) \(NaOH\) \(/CO _2\)	(S) Haloform

For the synthesis of benzoic acid the only correct combination is

For ${\mathrm{He}}^{+}$, a transition takes place from the orbit of radius $105.8\mathrm{pm}$ to the orbit of radius $26.45\mathrm{pm}$. The wavelength (in $\mathrm{nm}$ ) of the emitted photon during the transition is
Bohr radius, $\mathrm{a}=52.9 \mathrm{pm}$
Rydberg constant, ${\mathrm{R}}_{\mathrm{H}}=2.2\times {10}^{-18} \mathrm{J}$
Planck's constant, $\mathrm{h}=6.6\times {10}^{-34}\mathrm{Js}$
Speed of light, $\mathrm{c}=3\times {10}^8 {\mathrm{ms}}^{-1}$ ]

${\mathrm{H}}_2 \mathrm{S}$ ($5$ moles) reacts completely with acidified aqueous potassium permanganate solution. In this reaction, the number of moles of water produced is $\mathbf{x}$, and the number of moles of electrons involved is $\mathbf{y}$. The value of $(\mathrm{x}+\mathrm{y})$ is

In an atom, the total number of electrons having quantum numbers $\mathrm{n}=4,\mathrm{ }\left|{\mathrm{m}}_{\mathcal{l}}\right|=1$ and ${\mathrm{m}}_{\mathrm{s}}=–1/2$ is

The ${\mathrm{K}}_{\mathrm{sp}}$ of ${\text{Ag}}_2{\text{CrO}}_4$ is $1.1\times 10^{-12}$ at $298 \mathrm{K}$. The solubility (in $\mathrm{mol} {\mathrm{L}}^{-1}$) of ${\text{Ag}}_2\mathrm{CrO}{}_4$ in a $0.1 \mathrm{M} {\text{AgNO}}_3$ solution is

Consider a helium $\left(\mathrm{He}\right)$ atom that absorbs a photon of wavelength $330 \mathrm{nm}$. The change in the velocity (in $\mathrm{cm} {\mathrm{s}}^{-1}$) of $\mathrm{He}$ atom after the photon absorption is ______ .
(Assume: Momentum is conserved when photon is absorbed.
Use: Planck constant $=6.6\times {10}^{-34} \mathrm{J} \mathrm{s}$, Avocados number $=6\times {10}^{23}{ \mathrm{mol}}^{-1}$, Molar mass of $\mathrm{He}=4 \mathrm{g}{ \mathrm{mol}}^{-1}$)

Oxidation states of the metal in the minerals haematite and magnetite, respectively, are

Paragraph:
The amount of energy required to break a bond is same as the amount of energy released when the same bond is formed. In gaseous state, the energy required for homolytic cleavage of a bond is called Bond Dissociation Energy (BDE) or Bond Strength. BDE is affected by \(s\)-character of the bond and the stability of the radicals formed. Shorter bonds are typically stronger bonds. BDEs for some bonds are given below:





Question:
\(\mathrm{CH}_{4}(\mathrm{~g})+\mathrm{Cl}_{2}(\mathrm{~g}) \stackrel{\text { light }}{\longrightarrow} \mathrm{CH}_{3} \mathrm{Cl}(\mathrm{g})+\mathrm{HCl}(\mathrm{g})\) the correct statement is

Tangent is drawn at any point \(P\) of a curve which passes through \((1,1)\) cutting \(X\)-axis and \(Y\)-axis at \(A\) and \(B\), respectively. If \(A P: B P=3: 1\), then

Let $O$ be the origin and let $PQR$ be an arbitrary triangle. The point$S$ is such that $\overrightarrow{OP}.\overrightarrow{OQ}+\overrightarrow{OR}.\overrightarrow{OS}=\overrightarrow{OR}.\overrightarrow{OP}+\overrightarrow{OQ}.\overrightarrow{OS}=\overrightarrow{OQ}.\overrightarrow{OR}+\overrightarrow{OP}.\overrightarrow{OS}$ then triangle $PQR$ has $S$ as its

The slope of the tangent to the curve ${\left(y-x^5\right)}^2=\text{x}{\left(1+{\text{x}}^2\right)}^2$ at the point (1, 3) is ________.

Parallel rays of light of intensity $\mathrm{I}=912\mathrm{ }\mathrm{W}{\mathrm{m}}^{-2}$ are incident on a spherical black body kept in surroundings of temperature 300 K. Take Stefan-Boltzmann constant $\mathrm{\sigma }=5.7\times {10}^{-8}\mathrm{ }\mathrm{W}{\mathrm{m}}^{-2}\mathrm{ }{\mathrm{K}}^{-4}$ and assume that the energy exchange with the surroundings is only through radiation. The final steady state temperature of the black body is close to

The correct statement(s) about the compound given below is are