Among the following, the correct statement(s) about polymers is(are)

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Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately \(6.023 \times 10^{23}\) ) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following example illustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.
A \(4.0\) molar aqueous solution of \(\mathrm{NaCl}\) is prepared and \(500 \mathrm{~mL}\) of this solution is electrolysed. This leads to the evolution of chlorine gas at one of electrodes (atomic mass: \(\mathrm{Na}=23, \mathrm{Hg}=200 ; 1\) faraday \(=96500\) coulombs).
Question:
If the cathode is a Hg electrode, the maximum weight \((g)\) of amalgam formed from this solution is

If the distribution of molecular speeds of a gas is as per the figure shown below, then the ratio of the most probable, the average, and the root mean square speeds, respectively, is

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\(RCONH _2\) is converted into \(RNH _2\) by means of Hofmann bromamide degradation.

In this reaction, \(R \mathrm{CONHBr}\) is formed from which this reaction has derived its name. Electron donating group at phenyl activates the reaction. Hofmann degradation reaction is an intramolecular reaction.
Question:
Which is the rate determining step in Hofmann bromamide degradation?

Choose the correct reason(s) for the stability of the lyophobic colloidal particles.

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The concentration of potassium ions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. A simple model for such a concentration cell involving a metal \(\mathrm{M}\) is :
\(
M(s) \mid M^{+}(\alpha q ; 0.05 \text { molar }) \| M^{+}(a q ; 1 \text { molar })\) \(\mid M(s)
\)
For the above electrolytic cell the magnitude of the cell potential \(\left|E_{\text {cell }}\right|=70 \mathrm{mV}\).
Question:
If the \(0.05\) molar solution of \(M^{+}\)is replaced by a \(0.0025\) molar \(M^{+}\) solution, then the magnitude of the cell potential would be

The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is \(\left[a_{0}\right.\) is Bohr radius \(]\) :

The value of \(n\) in the molecular formula \(\mathrm{Be}_n \mathrm{Al}_2 \mathrm{Si}_6 \mathrm{O}_{18}\) is

Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the $n^{\mathrm{t}\mathrm{h}}$ orbit of the atom and List-II contains options showing how they depend on $n$ .
 

List - I	List - II
(I) Radius of the $n^{\mathrm{t}\mathrm{h}}$ orbit	$\left(\mathrm{P}\right)$ $\propto n^{-2}$
(II) Angular momentum of the electron in the $n^{th}$ orbit	$\left(\mathrm{Q}\right)$ $\propto n^{-1}$
(III) Kinetic energy of the electron in the $n^{\mathrm{t}\mathrm{h}}$ orbit	$\left(\mathrm{R}\right)$ $\propto n^0$
(IV) Potential energy of the electron in the $n^{\mathrm{t}\mathrm{h}}$ orbit	$\left(\mathrm{S}\right)$ $\propto n^1$
	$\left(\mathrm{T}\right)$ $\propto n^2$
	$\left(\mathrm{U}\right)$ $\propto n^{1/2}$

Which of the following options has the correct combination considering List-I and List-II?

A soft plastic bottle, filled with water of density \(1 \mathrm{gm} / \mathrm{cc}\), carries an inverted glass test-tube with some air (ideal gas) trapped as shown in the figure. The test-tube has a mass of \(5 \mathrm{gm}\), and it is made of a thick glass of density \(2.5 \mathrm{gm} / \mathrm{cc}\). Initially the bottle is sealed at atmospheric pressure \(p_{0}=10^{5} \mathrm{~Pa}\) so that the volume of the trapped air is \(v_{0}=3.3 \mathrm{cc}\). When the bottle is squeezed from outside at constant temperature, the pressure inside rises and the volume of the trapped air reduces. It is found that the test tube begins to sink at pressure \(p_{0}+\Delta p\) without changing its orientation. At this pressure, the volume of the trapped air is \(v_{0}-\Delta v\).
Let \(\Delta v=X\) cc and \(\Delta p=Y \times 10^{3} \mathrm{~Pa}\).

The value of $X$is ____.

The wave function, ${\mathrm{\psi }}_{\mathrm{n},\mathrm{}\mathrm{l},\mathrm{}{\mathrm{m}}_{\mathrm{l}}}$ is a mathematical function whose value depends upon spherical polar coordinates $\left(\mathrm{r},\mathrm{}\mathrm{\theta },\mathrm{}\mathrm{\varphi }\right)$ of the electron and characterized by the quantum numbers $\mathrm{n},\mathrm{}\mathrm{l}$ and ${\mathrm{m}}_{\mathrm{l}}$ . Here $\mathrm{r}$ is the distance from the nucleus, $\mathrm{\theta }$ is colatitude and $\mathrm{\varphi }$ is azimuth. In the mathematical functions given in the Table, $\mathrm{Z}$is the atomic number and ${\mathrm{a}}_{\mathrm{o}}$ is Bohr radius

Column 1	Column 2	Column 3
(I) 1s orbital	\(\text {(i) } \psi_{ n , 1, m_1}\) \(\propto\left(\frac{ Z }{ a _{ o }}\right)^{\frac{3}{2}} e ^{-\left(\frac{ Zr }{ e _{ o }}\right)}\)	(P)
(II) 2s orbital	(ii) One radial node	(Q) Probability density at the nucleus \(\propto \frac{1}{ a _{ o }^3}\).
(III) \(2 p _{ z }\) orbital	\(\text {(iii) } \psi_{ n }, 1, m_{ l }\) \(\propto\left(\frac{ Z }{ a _{ o }}\right)^{\frac{5}{2}} re ^{-\left(\frac{ Zr }{2 a _{ o }}\right)} \cos \theta\)	(R) Probability density is maximum at the nucleus.
(IV) \(3 d_{ z }^2\) orbital	(iv) \(x y\)-plane is a nodal plane	(S) Energy needed to excite an electron from \(n =2\) state to \(n =4\) state is \(\frac{27}{32}\) times the energy needed to excite are electron from \(n =2\) state to \(n =6\) state.

For hydrogen atom, what is the only CORRECT combination?

Positive and negative point charges of equal magnitude are kept at \(\left(0,0, \frac{a}{2}\right)\) and \(\left(0,0, \frac{-a}{2}\right)\), respectively. The work done by the electric field when another positive point charge is moved from \((-a, 0,0)\) to \((0, a, 0)\) is

A symmetric star shaped conducting wire loop is carrying a steady state current $I$ as shown in the figure. The distance between the diametrically opposite vertices of the star is $4a$ .