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AP EAMCET · Chemistry · Amines

Predict respectively ' \(X\) ' and ' \(Y\) ' in the following reactions.
\(\mathrm{Ar}-\mathrm{NH}_2 \stackrel{x}{\longrightarrow} \mathrm{Ar}-\stackrel{+}{\mathrm{N}} \equiv \mathrm{NCl}^{-} \stackrel{y}{\longrightarrow} \mathrm{Ar}-\mathrm{Cl}\)

  1. A \(\mathrm{NaNO}_3\) and \(\mathrm{Cl}_2\)
  2. B \(\mathrm{NaNO}_3-\mathrm{HCl}\) and \(\mathrm{HCl}\)
  3. C \(\mathrm{NaNO}_2-\mathrm{HCl}\) and \(\mathrm{Cu} / \mathrm{HCl}\)
  4. D \(\mathrm{NaNO}_2-\mathrm{HCl}\) and \(\mathrm{NaNH}_2\)
Verified Solution

Answer & Solution

Correct Answer

(C) \(\mathrm{NaNO}_2-\mathrm{HCl}\) and \(\mathrm{Cu} / \mathrm{HCl}\)

Step-by-step Solution

Detailed explanation

The sequence of reaction is