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AP EAMCET · Chemistry · Carboxylic Acid Derivatives

Acetic acid on heating with \(\mathrm{NH}_3\) forms \(A\). When \(A\) reacts with \(\mathrm{LiAlH}_4\) followed by hydrolysis gives \(B\). When \(B\) is heated with chloroform in \(\mathrm{KOH}\) medium gives \(C\). What are \(B\) and \(C\) respectively?

  1. A \(\mathrm{CH}_3 \mathrm{CONH}_2, \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NC}\)
  2. B \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2, \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NC}\)
  3. C \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2, \mathrm{CH}_3 \mathrm{COOH}\)
  4. D \(mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{NH}_2, \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NC}\)
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(B) \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2, \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NC}\)

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