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JEE Mains · Chemistry · STD 12 - 2. Electrochemistry

एक वैद्युतरासायनिक सेल \(Sn ( s )\left| Sn ^{2+}( aq , 1 M ) \| Pb ^{2+}( aq , 1 M )\right| Pb ( s )\) के लिए, जब सेल साम्यावस्था को प्राप्त करता है, तो अनुपात \(\frac{\left[ Sn ^{2+}\right]}{\left[ Pb ^{2+}\right]}\) है ..............(दिया गया है \(E _{ Sn ^{2+} \mid Sn }^{0}=-0.14 \,V\), \(\left. E _{ Pb ^{2+} \mid Pb _{ b }}^{0}=-0.13 \,V , \frac{2.303 RT }{ F }=0.06\right)\)

  1. A \(2.15\)
  2. B \(3.33\)
  3. C \(1.67\)
  4. D \(4.33\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(2.15\)

Step-by-step Solution

Detailed explanation

Cell reaction is \(\mathrm{Sn}(\mathrm{s})+\mathrm{Pb}^{+2}(\mathrm{aq}) \rightarrow \mathrm{Sn}^{+2}(\mathrm{aq})+\mathrm{Pb}(\mathrm{s})\dots (1)\) Apply Nernst equation:…
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