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JEE Mains · Chemistry · STD 12 - 2. Electrochemistry

अभिक्रिया \(\frac{1}{2} \mathrm{H}_2(\mathrm{~g})+\mathrm{AgCl}(\mathrm{s}) \rightleftharpoons \mathrm{H}^{+}(\mathrm{aq})+\mathrm{Cl}^{-}(\mathrm{aq})+\mathrm{Ag}(\mathrm{s})\) दिये गये किस गैल्वानिक सेल में होगी \((1)\) \(\mathrm{Pt}\left|\mathrm{H}_2(\mathrm{~g})\right| \mathrm{KCl}\left(\mathrm{sol}^{\mathrm{n}}\right)|\mathrm{AgCl}(\mathrm{s})| \mathrm{Ag}\) \((2)\) \(\mathrm{Pt}\left|\mathrm{H}_2(\mathrm{~g})\right| \mathrm{HCl}\left(\mathrm{sol}^n\right)|\mathrm{AgCl}(\mathrm{s})| \mathrm{Ag}\) \((3)\) \(\mathrm{Ag}|\mathrm{AgCl}(s)| \mathrm{KCl}\left(\mathrm{sol}^n\right)|\mathrm{AgCl}(\mathrm{s})| \mathrm{Ag}\) \((4)\) \(\mathrm{Pt}\left|\mathrm{H}_2(\mathrm{~g})\right| \mathrm{HCl}\left(\mathrm{sol}^{\mathrm{n}}\right)\left|\mathrm{AgNO}_3\left(\mathrm{sol}^{\mathrm{n}}\right)\right| \mathrm{Ag}\)

  1. A \(Pt \mid H _2\) (g) \(\left| KCl \left( sol ^{ n }\right)\right| \operatorname{AgCl}( s ) \mid Ag\)
  2. B \(Pt \left| H _2( g )\right| HCl \left( sol ^{ n }\right)| AgCl ( s )| Ag\)
  3. C \(Ag | AgCl ( s )| KCl \left( sol ^{ I }\right)| AgCl ( s )| Ag\)
  4. D \(Pt \left| H _2( g )\right| HCl \left( sol ^{ n }\right)\left| AgNO _3\left( sol ^{ n }\right)\right| Ag\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(Pt \left| H _2( g )\right| HCl \left( sol ^{ n }\right)| AgCl ( s )| Ag\)

Step-by-step Solution

Detailed explanation

Anode : \(\frac{1}{2} H _2( g ) \rightleftharpoons H ^{+}( aq )+ e ^{-}\) Cathode : \(AgCl ( s )+ e ^{-} \rightarrow Ag ( s )+ Cl ^{-}( aq )\)
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