WBJEE · Chemistry · Chemical Kinetics

Which of the following would give a linear plot?
(\(k\) is the rate constant of an elementary reaction and \(\mathrm{T}\) is temp. in absolute scale)

A k vs T
B \(\mathrm{k~vs~} 1 / \mathrm{T}\)
C In k vs T
D \(\ln \mathrm{k~vs~} 1 / \mathrm{T}\)

Verified Solution

Answer & Solution

Correct Answer

(D) \(\ln \mathrm{k~vs~} 1 / \mathrm{T}\)

Step-by-step Solution

Detailed explanation

Hint : Arrhenius equation gives us \(\begin{aligned} & k=A e^{-E_a / R T} \\ & \ln k=\ln A-\frac{E_a}{R}\left(\frac{1}{T}\right) \\ & y=c-m x \end{aligned}\)

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

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Which of the following would give a linear plot?(\(k\) is the rate constant of an elementary reaction and \(\mathrm{T}\) is temp. in absolute scale)

Step-by-step Solution

Which of the following would give a linear plot?
(\(k\) is the rate constant of an elementary reaction and \(\mathrm{T}\) is temp. in absolute scale)