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WBJEE · Chemistry · d and f Block Elements

What will be the change in acidity if
(i) \(\mathrm{CuSO}_4\) is added in saturated \(\left(\mathrm{NH}_4\right)_2 \mathrm{SO}_4\) solution
(ii) \(\mathrm{SbF}_5\) is added in anhydrous HF

  1. A increase, increase
  2. B decrease, decrease
  3. C increase, decrease
  4. D decrease, increase
Verified Solution

Answer & Solution

Correct Answer

(A) increase, increase

Step-by-step Solution

Detailed explanation

Hint : i) \(\mathrm{Cu}^{2+}{ }_{(\mathrm{aq})}+4 \mathrm{NH}_4{ }^{+}{ }_{(\mathrm{aq})} \rightarrow\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{+2}+4 \mathrm{H}^{+}{ }_{(\mathrm{aq})}\) Formation of stable \(\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{+2}\)…