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WBJEE · Chemistry · p Block Elements (Group 13 & 14)

The main reason that \(\mathrm{SiCl}_{4}\) is easily hydrolysed as compared to \(\mathrm{CCl}_{4}\) is that

  1. A \(\mathrm{Si}-\mathrm{Cl}\) bond is weaker than \(\mathrm{C}-\mathrm{Cl}\) bond
  2. B \(\mathrm{SiCl}_{4}\) can form hydrogen bonds
  3. C \(\mathrm{SiCl}_{4}\) is covalent
  4. D Si can extend its coordination number beyond four
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Correct Answer

(D) Si can extend its coordination number beyond four

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Detailed explanation

It is less reactive than other oxides of chlorine and does not react with \(P, S,\) coal or paper at room temperature. The main reason that \(\mathrm{SiCl}_{4}\) is easily hydrolysed as compared to \(\mathrm{CCl}_{4}\), is that Si can extend its coordination number beyond four…