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WBJEE · Chemistry · Carboxylic Acid Derivatives

The ease of hydrolysis in the compounds \(\mathrm{CH}_{3} \mathrm{COCl}(\mathrm{I}), \mathrm{CH}_{3}-\mathrm{CO}-\mathrm{O}-\mathrm{COCH}_{3}(\mathrm{II})\)
\(\mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}(\mathrm{III})\) and \(\mathrm{CH}_{3} \mathrm{CONH}_{2}\) (IV) is of
the order

  1. A \(I>II>III>IV\)
  2. B \(IV>III>II>I\)
  3. C \(I>II>IV>III\)
  4. D \(II>I>IV>III\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(I>II>III>IV\)

Step-by-step Solution

Detailed explanation

The ease of hydrolysis of carbonyl compounds depend on the group attached to the carbonyl carbon. Among the given options, chlorine \((-\) Cl) group is clectron withdrawing group which makes the carbonyl group electrophilic. Hence, hydrolysis can occur most easily. The order for…