WBJEE · Chemistry · Classification of Elements and Periodicity in Properties

Suppose a gaseous mixture of \(\mathrm{He}, \mathrm{Ne}, \mathrm{Ar}\) and \(\mathrm{Kr}\) is treated with photons of the frequency appropriate to ionize Ar. What ion(s) will be present in the mixture?

A \(\mathrm{Ar}^{+}\)
B \(\mathrm{Ar}^{+}+\mathrm{Kr}\)
C \(\mathrm{Ar}^{+}+\mathrm{He}^{+}+\mathrm{Ne}^{+}\)
D \(\mathrm{He}^{+}+\mathrm{Ar}^{+}+\mathrm{Kr}^{+}\)

Verified Solution

Answer & Solution

Correct Answer

(B) \(\mathrm{Ar}^{+}+\mathrm{Kr}\)

Step-by-step Solution

Detailed explanation

Hint: \(\mathrm{He} > \mathrm{Ne} > \mathrm{Ar} > \mathrm{Kr} > \mathrm{Xe} > \mathrm{Rn}\) (Order of lonization energy) Energy of photon is sufficient to ionize \(\mathrm{Ar}\), hence \(\mathrm{Kr}\) will also ionize. Therefore mixture contains \(\mathrm{Ar}^{+}\)and…

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Explore more questions on app

From WBJEE

Explore more questions on app