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WBJEE · Chemistry · General Organic Chemistry

Among the following carbocations :
(I) \(\mathrm{Ph}_{2}\stackrel{+}{\mathrm{C}} \mathrm{CH}_{2} \mathrm{Me}(\mathrm{II}) \mathrm{Ph} \mathrm{CH}_{2} \mathrm{CH}_{2} \stackrel{+}{\mathrm{C}} \mathrm{HPh}\)
(III) \(\mathrm{Ph}_{2} \mathrm{CH} \stackrel{+}{\mathrm{C}} \mathrm{HMe}\) (IV) \(\mathrm{Ph}_{2} \mathrm{C}(\mathrm{Me}) \stackrel{+}{\mathrm{C}} H_{2}\) the order of stability is :

  1. A IV \(>\mathrm{II}>\mathrm{I}>\mathrm{III}\)
  2. B \(I>\mathrm{II}>\mathrm{III}>\mathrm{IV}\)
  3. C II \(>I>\mathrm{IV}>\mathrm{III}\)
  4. D \(\mathrm{I}>\mathrm{TV}>\mathrm{III}>\mathrm{II}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(I>\mathrm{II}>\mathrm{III}>\mathrm{IV}\)

Step-by-step Solution

Detailed explanation

The order of stability of carbocation is \(3^{\circ}\) benzylic \(>2^{\circ}\) benzylic \(>2^{*}>1^{*}\) Thus, the correct order of stability will be