TS EAMCET · Chemistry · Alcohols Phenols and Ethers

The reagent that can reduce the carboxylic acid group to the corresponding alcohol is

A ${NaBH}_{4} / H_{3} O^{+}$
B $B_{2} H_{6} / H_{3} O^{+}$
C $Zn - Hg / conc . HCl$
D $H_{2}, Pd / C$

Verified Solution

Answer & Solution

Correct Answer

(B) $B_{2} H_{6} / H_{3} O^{+}$

Step-by-step Solution

Detailed explanation

Carboxylic acids are reduced to primary alcohols by lithium aluminium hydride or better with diborane. Diborane does not easily reduce functional groups such as ester, nitro, halo, etc. Sodium borohydride does not reduce the carboxyl group. The carbonyl group of aldehydes and…

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Following lists contain reactions and their corresponding equilibrium constants at different temperatures:

List - I (Reaction)	List - II $(K_{p})$
$2 {SO}_{2} (g) + O_{2} (g) ⇌ 2 {SO}_{3} (g) at 298 K$	$4.0 \times 10^{24}$
$2 {SO}_{2} (g) + O_{2} (g) ⇌ 2 {SO}_{3} (g) at 700 K$	$3.0 \times 10^{4}$
$N_{2} O_{4} (g) ⇌ 2 {NO}_{2} (g) at 298 K$	$0.98$
$N_{2} O_{4} (g) ⇌ 2 {NO}_{2} (g) at 500 K$	$1700$

∆ H_{1}^{0} and ∆ H_{2}^{0}

are the standard enthalpies for the reactions

2 {SO}_{2} + O_{2} ⇌ 2 {SO}_{3} and N_{2} O_{4} ⇌ 2 {NO}_{2}

respectively, then:

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