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TS EAMCET · Chemistry · Amines

The major products P and Q from the following reactions are

  1. A \(\mathrm{P}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{NH}_2 \quad ; \quad \mathrm{Q}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{NH}_2\)
  2. B \(\mathrm{P}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{NH}_2 \quad ; \quad \mathrm{Q}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{NH}_2\)
  3. D \(\mathrm{P}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{CN} \quad ; \quad \mathrm{Q}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{Br}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(\mathrm{P}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{NH}_2 \quad ; \quad \mathrm{Q}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{NH}_2\)

Step-by-step Solution

Detailed explanation

\( \text{C}_6\text{H}_5\text{N}_2^+\text{Cl}^- \xrightarrow{\text{CuCN/KCN}} \text{P} = \text{C}_6\text{H}_5\text{CN} \) \( \text{C}_6\text{H}_5\text{CN} \xrightarrow{\text{LiAlH}_4/\text{H}_2\text{O}} \text{Q} = \text{C}_6\text{H}_5\text{CH}_2\text{NH}_2 \)