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TS EAMCET · Chemistry · Chemical Kinetics

The decomposition of benzene diazonium chloride is a first order reaction. The time taken for its decomposition of \(\frac{1}{4}\) and \(\frac{1}{10}\) of its initial concentration are \(t_{1 / 4}\) and \(t_{1 / 10}\) respectively. The value of \(\frac{t_{1 / 4}}{t_{1 / 10}} \times 100\) is (Given : \(\log 2=0.3\) )

  1. A 60
  2. B 30
  3. C 90
  4. D 45
Verified Solution

Answer & Solution

Correct Answer

(A) 60

Step-by-step Solution

Detailed explanation

\(\begin{aligned} & \mathrm{k}=\frac{2.303}{\mathrm{t}_{\frac{1}{4}}^4} \log \frac{\mathrm{a}}{\frac{\mathrm{a}}{4}}.....(i) \\ & \mathrm{k}=\frac{2.303}{\mathrm{t}_{\frac{1}{4}}^{10}} \log \frac{\mathrm{a}}{\frac{\mathrm{a}}{10}}.. \end{aligned}\)…