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TS EAMCET · Chemistry · Haloalkanes and Haloarenes

Arrange the following bromides in the order of reactivity in undergoing \(\mathrm{S}_{\mathrm{N}} 1\) reaction.

  1. A i \(>\) iii \(>\) ii \(>\) iv
  2. B iv \(>\) ii \(>\) iii \(>\) i
  3. C i \(>\) ii \(>\) iii \(>\) iv
  4. D ii \(>\) iv \(>\) iii \(>\) i
Verified Solution

Answer & Solution

Correct Answer

(A) i \(>\) iii \(>\) ii \(>\) iv

Step-by-step Solution

Detailed explanation

As stability of carbocation is in order \(\rightarrow 3^{\circ}>20>1^{\circ}\), so the order of \(S_N 1\) reaction in alkyl halide. (i) \(3^{\circ}>2^{\circ}>1^{\circ}\) So, the correct order is \(i i i>i i>i v\).
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