TS EAMCET · Chemistry · Amines
Aniline is not the major product in one of the following reactions. Identify that reaction
- A \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{OH}+\mathrm{NH}_3 \frac{\mathrm{ZnCl}_2}{300^{\circ} \mathrm{C}}\)
- B \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{NO}_2+\mathrm{Zn}\) powder \(\stackrel{\text { alcoholic } \mathrm{KOH}}{\longrightarrow}\)
- C \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{Cl}+\mathrm{NH}_3 \underset{\mathrm{Cu}_2 \mathrm{O}}{\stackrel{200^{\circ} \mathrm{C}}{\longrightarrow}}\) high pressure
- D \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{NO}_2+6(\mathrm{H})+\underset{\mathrm{HCl}}{\stackrel{\mathrm{Fe}+\mathrm{H}_2 \mathrm{O}}{\longrightarrow}}\)
Answer & Solution
Correct Answer
(B) \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{NO}_2+\mathrm{Zn}\) powder \(\stackrel{\text { alcoholic } \mathrm{KOH}}{\longrightarrow}\)
Step-by-step Solution
Detailed explanation
Aniline is not obtained as a major product by the reaction. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{NO}_2+\mathrm{Zn}_{\text {powder }} \stackrel{\text { alcoholic } \mathrm{KOH}}{\longrightarrow}\)
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