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TS EAMCET · Chemistry · Coordination Compounds

A complex compound of \(\mathrm{Co}^{3+}\) with molecular formula \(\mathrm{CoCl}_{\mathrm{x}} \cdot \mathrm{yNH}_3\) gives a total of 3 ions when dissolved in water. How many \(\mathrm{Cl}^{-}\)ions satisfy both primary and secondary valencies in this complex?

  1. A 3
  2. B 1
  3. C 4
  4. D zero
Verified Solution

Answer & Solution

Correct Answer

(B) 1

Step-by-step Solution

Detailed explanation

As cobalt is present as \(\mathrm{Co}^{3+}\) and co-ordination number of cobalt is 6 , the molecular formula of compound should be \(\mathrm{CoCl}_3 \cdot \mathrm{yNH}_3\). Now, as it gives a total of 3 ions when dissolved in water, its structural formula must be…