ExamBro
ExamBro
NEET · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

In which of the following processes entropy increases? \(A\). A liquid evaporates to vapour. \(B\). Temperature of a crystalline solid lowered from \(130 \mathrm{~K}\) to \(0 \mathrm{~K}\). \(C\). \(2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_2 \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\) \(D\). \(\mathrm{Cl}_{2(g)} \rightarrow 2 \mathrm{Cl}_{(g)}\) Choose the correct answer from the options given below:

  1. A  \(A, B\) and \(D\)
  2. B  \(A, C\) and \(D\)
  3. C  \(C\) and \(D\)
  4. D  \(A\) and \(C\)
Verified Solution

Answer & Solution

Correct Answer

(B)  \(A, C\) and \(D\)

Step-by-step Solution

Detailed explanation

When a liquid evaporates to vapour entropy increases.
\(2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_2 \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\)
Number of gaseous product molecules increases so entropy increases.
\(\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{Cl}_{(\mathrm{g})}\)
\(1 \mathrm{~mole}_{\mathrm{Cl}_{2(g)}}\) form \(2 \mathrm{~mol} \mathrm{Cl}_{(\mathrm{g})}\). So entropy increases.