NEET · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry
In which of the following processes entropy increases? \(A\). A liquid evaporates to vapour. \(B\). Temperature of a crystalline solid lowered from \(130 \mathrm{~K}\) to \(0 \mathrm{~K}\). \(C\). \(2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_2 \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\) \(D\). \(\mathrm{Cl}_{2(g)} \rightarrow 2 \mathrm{Cl}_{(g)}\) Choose the correct answer from the options given below:
- A \(A, B\) and \(D\)
- B \(A, C\) and \(D\)
- C \(C\) and \(D\)
- D \(A\) and \(C\)
Answer & Solution
Correct Answer
(B) \(A, C\) and \(D\)
Step-by-step Solution
Detailed explanation
When a liquid evaporates to vapour entropy increases.
\(2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_2 \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\)
Number of gaseous product molecules increases so entropy increases.
\(\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{Cl}_{(\mathrm{g})}\)
\(1 \mathrm{~mole}_{\mathrm{Cl}_{2(g)}}\) form \(2 \mathrm{~mol} \mathrm{Cl}_{(\mathrm{g})}\). So entropy increases.
\(2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_2 \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\)
Number of gaseous product molecules increases so entropy increases.
\(\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{Cl}_{(\mathrm{g})}\)
\(1 \mathrm{~mole}_{\mathrm{Cl}_{2(g)}}\) form \(2 \mathrm{~mol} \mathrm{Cl}_{(\mathrm{g})}\). So entropy increases.
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