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KCET · Chemistry · Haloalkanes and Haloarenes

Which one of the following forms propane nitrile as the major product?

  1. A Ethyl bromide + alcoholic KCN
  2. B Propyl bromide + alcoholic KCN
  3. C Propyl bromide \(+\) alcoholic AgCN
  4. D Ethyl bromide \(+\) alcoholic AgCN
Verified Solution

Answer & Solution

Correct Answer

(A) Ethyl bromide + alcoholic KCN

Step-by-step Solution

Detailed explanation

When ethyl bromide reacts with alcoholic KCN, propane nitrile is obtained as main product.
\(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}+\mathrm{Alc} . \mathrm{KCN} \longrightarrow \underset{\text { propane nitrile }}{\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CN}}\)