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KCET · Chemistry · Ionic Equilibrium

The correct arrangement of the species in the decreasing order of the bond length between
carbon and oxygen in them is

  1. A \( \mathrm{CO}_{2}, \mathrm{HCO}_{2}^{-}, \mathrm{CO}, \mathrm{CO}_{3}^{2-} \)
  2. B \( \mathrm{CO}, \mathrm{CO}_{3}{ }^{2-}, \mathrm{CO}_{2}, \mathrm{HCO}_{2} \)
  3. C \( \mathrm{CO}, \mathrm{CO}_{2}, \mathrm{HCO}_{2}^{-}, \mathrm{CO}_{3}^{2-} \)
  4. D \( \mathrm{CO}_{3}{ }^{2-}, \mathrm{HCO}_{2}{ }^{-}, \mathrm{CO}_{2}, \mathrm{CO} \)
Verified Solution

Answer & Solution

Correct Answer

(D) \( \mathrm{CO}_{3}{ }^{2-}, \mathrm{HCO}_{2}{ }^{-}, \mathrm{CO}_{2}, \mathrm{CO} \)

Step-by-step Solution

Detailed explanation

We know Bond order \( \propto \frac{1}{\text { Bond length }} \)
CO molecule have \( 3 \) bonds between \( C \) and \( O \).
\(
C=O
\)
\( \mathrm{CO}_{2} \) molecule have \( 2 \) double bonds between \( \mathrm{C} \) and \( \mathrm{O} \)
\(
O=C=O
\)
\( \mathrm{CO}_{3}{ }^{2-} \) ion have \( 3 \) partial double bonds between \( \mathrm{C} \) and \( \mathrm{O} \), due to resonance.

\( \mathrm{HCO}_{2}{ }^{-} \)ion also show resonance, but due to the presence of hydrogen atom attached to carbon atom it has less
resonance hybrid, therefore, \( \mathrm{HCO}_{2}{ }^{-} \)ion have greater bond order than \( \mathrm{CO}_{3}{ }^{2-} \)

Hence, the correct decreasing order of bond length is \( \mathrm{CO}_{3}{ }^{2-}, \mathrm{HCO}_{2}{ }^{-}, \mathrm{CO}_{2}, \mathrm{CO} \)