KCET · Chemistry · States of Matter

One mole of oxygen at \(273 \mathrm{~K}\) and one mole of sulphur dioxide at \(546 \mathrm{~K}\) are taken in two separate containers, then,

A kinetic energy of \(\mathrm{O}_{2}>\) kinetic energy of \(\mathrm{SO}_{2}\)
B kinetic energy of \(\mathrm{O}_{2} < \) kinetic energy of \(\mathrm{SO}_{2}\)
C kinetic energy of both are equal
D None of the above

Verified Solution

Answer & Solution

Correct Answer

(B) kinetic energy of \(\mathrm{O}_{2} < \) kinetic energy of \(\mathrm{SO}_{2}\)

Step-by-step Solution

Detailed explanation

\(\mathrm{KE}=\frac{3}{2} R T\) \(\mathrm{KE} \propto T\)
\[
\begin{aligned}
& \frac{\mathrm{KE}_{\mathrm{O}_{2}}}{\mathrm{KE}_{\mathrm{SO}_{2}}}=\frac{T_{\mathrm{O}_{2}}}{T_{\mathrm{SO}_{2}}}=\frac{273}{546}=\frac{1}{2} \\
\mathrm{KE}_{\mathrm{SO}_{2}} &=2 \mathrm{KE}_{\mathrm{O}_{2}} \\
\therefore \quad \mathrm{KE}_{\mathrm{SO}_{2}} &>2 \mathrm{KE}_{\mathrm{O}_{2}}
\end{aligned}
\]

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

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