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KCET · Chemistry · Thermodynamics (C)

Lattice enthalpy for \(\mathrm{NaCl}\) is \(+788 \mathrm{~kJ} \mathrm{~mol}^{-1}\) and \(\Delta H_{\text {hyd }}^{\circ}=-784 \mathrm{~kJ} \mathrm{~mol}^{-1}\). Enthalpy of solution of \(\mathrm{NaCl}\) is

  1. A \(+572 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
  2. B \(+4 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
  3. C \(-572 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
  4. D \(-4 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(+4 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

Step-by-step Solution

Detailed explanation

\(\Delta H_{\text {sol }}=\Delta H_{\text {lattice }}+\Delta H_{\text {hydration }}\)
\(=788+(-784)=4 \mathrm{~kJ} \mathrm{~mol}^{-1}\)