KCET · Chemistry · Coordination Compounds
\( \left[\mathrm{Fe}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}_{3}\right] \) and \( \left[\mathrm{Fe}(\mathrm{O}-\mathrm{NO})_{} \mathrm{Cl}_{3}\right] \) shows
- A Linkage isomerism
- B Geometrical isomerism
- C Optical isomerism
- D Hydrate isomerism
Answer & Solution
Correct Answer
(A) Linkage isomerism
Step-by-step Solution
Detailed explanation
\( \left[\left(\mathrm{Fe}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}_{3}\right]\right. \) and \( \left[\mathrm{Fe}(\mathrm{O}-\mathrm{NO})_{2} \mathrm{Cl}_{3}\right] \) shows linkage isomerism because \( \mathrm{NO}_{2} \) is an ambidentate ligand, it can
link through both nitrogen and oxygen atom.
link through both nitrogen and oxygen atom.
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