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KCET · Chemistry · Coordination Compounds

Extraction of chlorine from brine solution is based on

  1. A Oxidation
  2. B Chlorination
  3. C Reduction
  4. D Acidification
Verified Solution

Answer & Solution

Correct Answer

(A) Oxidation

Step-by-step Solution

Detailed explanation

Chloride is obtained by the electrolysis of brine solution (conc. NaCl solution). Chlorine is liberated at the anode the sodium metal is liberated at the cathode and reacts with water to form \(\mathrm{NaOH}\) and \(\mathrm{H}_{2}\)
At anode oxidation takes place:
\[
\begin{array}{l}
\mathrm{Cl}^{-} \rightarrow \mathrm{Cl}+e^{-} \\
\mathrm{Cl}+\mathrm{Cl} \rightarrow \mathrm{Cl}_{2}
\end{array}
\]
At cathode reduction takes place:
\(\mathrm{Na}^{+}+e^{-} \rightarrow \mathrm{Na}\) \(2 \mathrm{Na}+2 \mathrm{H}_{2} \mathrm{O} \rightarrow 2 \mathrm{~N} a \mathrm{OH}+\mathrm{H}_{2}\)
Therefore, extraction of chlorine from brine solution is based on oxidation.