KCET · Chemistry · Biomolecules
Consider the following statements:
Statement-I: All monosaccharides are reducing sugars.
Statement-II: Sucrose can reduce ammoniacal silver nitrate solution.
Choose the correct answer from the options given below.
- A Both Statement I and Statement II are correct
- B Both Statement I and Statement II are incorrect
- C Statement I is correct but Statement II is incorrect
- D Statement I is incorrect but Statement II is correct
Answer & Solution
Correct Answer
(C) Statement I is correct but Statement II is incorrect
Step-by-step Solution
Detailed explanation
Statement-I is correct because all monosaccharides contain a free aldehyde or ketonic group in their open-chain structure, which allows them to act as reducing agents. Thus, all monosaccharides are reducing sugars.
Statement-II is incorrect because sucrose is a non-reducing sugar. In sucrose, the two monosaccharide units (glucose and fructose) are held together by a glycosidic linkage between C1 of \(\alpha\)-D-glucose and C2 of \(\beta\)-D-fructose. Since the reducing groups of both glucose and fructose are involved in glycosidic bond formation, sucrose does not have a free aldehyde or ketone group and cannot reduce ammoniacal silver nitrate solution (Tollens' reagent).
Therefore, Statement I is correct but Statement II is incorrect.
Answer: Statement I is correct but Statement II is incorrect
Statement-II is incorrect because sucrose is a non-reducing sugar. In sucrose, the two monosaccharide units (glucose and fructose) are held together by a glycosidic linkage between C1 of \(\alpha\)-D-glucose and C2 of \(\beta\)-D-fructose. Since the reducing groups of both glucose and fructose are involved in glycosidic bond formation, sucrose does not have a free aldehyde or ketone group and cannot reduce ammoniacal silver nitrate solution (Tollens' reagent).
Therefore, Statement I is correct but Statement II is incorrect.
Answer: Statement I is correct but Statement II is incorrect
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