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KCET · Chemistry · Biomolecules

Consider the following statements:
Statement-I: All monosaccharides are reducing sugars.
Statement-II: Sucrose can reduce ammoniacal silver nitrate solution.
Choose the correct answer from the options given below.

  1. A Both Statement I and Statement II are correct
  2. B Both Statement I and Statement II are incorrect
  3. C Statement I is correct but Statement II is incorrect
  4. D Statement I is incorrect but Statement II is correct
Verified Solution

Answer & Solution

Correct Answer

(C) Statement I is correct but Statement II is incorrect

Step-by-step Solution

Detailed explanation

Statement-I is correct because all monosaccharides contain a free aldehyde or ketonic group in their open-chain structure, which allows them to act as reducing agents. Thus, all monosaccharides are reducing sugars.

Statement-II is incorrect because sucrose is a non-reducing sugar. In sucrose, the two monosaccharide units (glucose and fructose) are held together by a glycosidic linkage between C1 of \(\alpha\)-D-glucose and C2 of \(\beta\)-D-fructose. Since the reducing groups of both glucose and fructose are involved in glycosidic bond formation, sucrose does not have a free aldehyde or ketone group and cannot reduce ammoniacal silver nitrate solution (Tollens' reagent).

Therefore, Statement I is correct but Statement II is incorrect.

Answer: Statement I is correct but Statement II is incorrect