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JEE Mains · Chemistry · STD 12 - 9. Amines

Which of the following reaction is an example of ammonolysis ?

  1. A \(C _{6} H _{5} COCl + C _{6} H _{5} NH _{2} \longrightarrow C _{6} H _{5} CONHC _{6} H _{5}\)
  2. B \(C _{6} H _{5} CH _{2} CN \stackrel{\text { [H] }}{\longrightarrow} C _{6} H _{5} CH _{2} CH _{2} NH _{2}\)
  3. C \(C _{6} H _{5} NH _{2} \stackrel{ HCl }{\longrightarrow} C _{6} H _{5} NH _{3} Cl ^{-}\)
  4. D \(C _{6} H _{5} CH _{2} Cl + NH _{3} \longrightarrow C _{6} H _{5} CH _{2} NH _{2}\)
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Correct Answer

(D) \(C _{6} H _{5} CH _{2} Cl + NH _{3} \longrightarrow C _{6} H _{5} CH _{2} NH _{2}\)

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Detailed explanation

The process of cleavage of the \(C - X\) bond by Ammonia molecule is known as ammonolysis. \(Ex : R - CH _{2}- Cl +\ddot{ N } H _{3} \longrightarrow R - CH _{2}- NH _{2}\)
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