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JEE Advanced · Chemistry · 7. Chemical Equilibrium

The thermal dissociation equilibrium of CaCO3s is studied under different conditions.
CaCO3sCaOs+CO2g
For this equilibrium, the correct statement(s) is/are

  1. A H is dependent on T.
  2. B K is independent of the initial amount of CaCO3.
  3. C K is dependent on the pressure of CO2 at a given T.
  4. D H is independent of the catalyst, if any.
Verified Solution

Answer & Solution

Correct Answer

(A) H is dependent on T.

Step-by-step Solution

Detailed explanation

Kirchoff's Equation-
ΔHT=ΔH+298TΔCpreacdT
Δ H reac is dependent on temperature.
K = CO 2 × 1 1   as solids are treated at unit activity. K is independent of initial amount of CaCO3.
Kp=pCO2(g) at a given temperature Kp depends only on temperature.
Δ H = E a for - E b back   A catalyst lowers only the activation energies & Δ H react is independent of catalyst.
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