In the following reaction sequence, the amount of $\text{D}$ (in g) formed from $10$ moles of acetophenone is ____.
(Atomic weights in $\text{g}\text{m}\text{o}{\text{l}}^{-1}:\text{H}=1,\text{C}=12,\text{N}=14,\text{O}=16,\text{B}\text{r}=80.$ The yield (%) corresponding to the product in each step is given in the parenthesis)

A solution when diluted with \(\mathrm{H}_2 \mathrm{O}\) and boiled, it gives a white precipitate. On addition of excess \(\mathrm{NH}_4 \mathrm{Cl} / \mathrm{NH}_4 \mathrm{OH}\), the volume of precipitate decreases leaving behind a white gelatinous precipitate. Identify the precipitate which dissolves in \(\mathrm{NH}_4 \mathrm{OH} / \mathrm{NH}_4 \mathrm{Cl}\).

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Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
The vapour pressure of the solution \(M\) is

Consider an ionic solid $\mathrm{MX}$, with $\mathrm{NaCl}$ structure. Construct a new structure $\left(\mathrm{Z}\right)$, whose unit cell is constructed from the unit cell of $\mathrm{MX}$, following the sequential instructions given below. Neglect the charge balance.
$\left(\mathrm{i}\right)$ Remove all the anions $\left(\mathrm{X}\right)$, except the central one.
$\left(\mathrm{ii}\right)$ Replace all the face centered cations $\left(\mathrm{M}\right)$, by anions $\left(\mathrm{X}\right)$.
$\left(\mathrm{iii}\right)$ Remove all the corner cations $\left(\mathrm{M}\right)$.
$\left(\mathrm{iv}\right)$ Replace the central anion $\left(\mathrm{X}\right)$, with cation $\left(\mathrm{M}\right)$.
The value of $\left(\frac{\mathrm{n}\mathrm{u}\mathrm{m}\mathrm{b}\mathrm{e}\mathrm{r}\mathrm{ }\mathrm{o}\mathrm{f}\mathrm{ }\mathrm{a}\mathrm{n}\mathrm{i}\mathrm{o}\mathrm{n}\mathrm{s}}{\mathrm{n}\mathrm{u}\mathrm{m}\mathrm{b}\mathrm{e}\mathrm{r}\mathrm{ }\mathrm{o}\mathrm{f}\mathrm{ }\mathrm{c}\mathrm{a}\mathrm{t}\mathrm{i}\mathrm{o}\mathrm{n}\mathrm{s}}\right)$ in $\mathrm{Z}$ is _____.

Match the rate expressions in LIST-I for the decomposition of \(\mathrm{X}\) with the corresponding profiles provided in LIST-II. \(X_s\) and \(\mathrm{k}\) are constants having appropriate units.

The reduction potential $\left({\mathrm{E}}^0\right.$, in $\left.\mathrm{V}\right)$ of ${\mathrm{MnO}}_4^{-}\left(\mathrm{aq}\right)/\mathrm{Mn}\left(\mathrm{s}\right)$ is
\(\left[\right.\)Given: \(E _{\left( MnO _4^{-}( aq ) / MnO _2(s)\right)}^{ o }=1.68 V ;\) \( E _{\left( MnO _2(s) / Mn ^{2+}( aq )\right)}^{ o }=\) \(1.21 V ; E _{\left( Mn ^{2+}( aq ) / Mn ( s )\right)}^{ o }\) \(=-1.03 V]\)
Truncate/round-off the value to TWO decimal places.

The reagent(s) for the following conversion,

is/are

Statement I A block of mass \(m\) starts moving on a rough horizontal surface with a velocity \(v\). It stops due to friction between the block and the surface after moving through a certain distance. The surface is now tilted to an angle of \(30^{\circ}\) with the horizontal and the same block is made to go up on the surface with the same initial velocity \(v\). The decrease in the mechanical energy in the second situation is smaller than that in the first situation.
Statement II The coefficient of friction between the block and the surface decreases with the increase in the angle of inclination.

The number of solutions of the pair of equations \(2 \sin ^2 \theta-\cos 2 \theta=0\) and \(2 \cos ^2 \theta-3 \sin \theta=0\) in the interval \([0,2 \pi]\) is

Let \(A B C\) be a triangle such that \(\angle A C B=\frac{\pi}{6}\) and let \(a, b\) and \(c\) denote the lengths of the sides opposite to \(A, B\) and \(C\) respectively. The value(s) of \(x\) for which \(a=x^2+x+1, b=x^2-1\) and \(c=2 x+1\) is (are)

Tangents are drawn to the hyperbola \(\frac{x^{2}}{9}-\frac{y^{2}}{4}=1\), parallel to the straight line \(2 x-y=1\). The points of contact of the tangents on the hyperbola are

Consider a system of three connected strings, \(S_1, S_2\) and \(S_3\) with uniform linear mass densities \(\mu \mathrm{kg} / \mathrm{m}\), \(4 \mu \mathrm{~kg} / \mathrm{m}\) and \(16 \mu \mathrm{~kg} / \mathrm{m}\), respectively, as shown in the figure. \(S_1\) and \(S_2\) are connected at the point \(P\), whereas \(S_2\) and \(S_3\) are connected at the point \(Q\), and the other end of \(S_3\) is connected to a wall. A wave generator O is connected to the free end of \(S_1\). The wave from the generator is represented by \(y=y_0\) \(\cos (\omega t-k x) \mathrm{cm}\), where \(y_0, \omega\) and \(k\) are constants of appropriate dimensions. Which of the following statements is/are correct:

Let $\left|X\right|$ denote the number of elements in set $X.$ Let $S=\left\{1, 2, 3, 4, 5, 6\right\}$ be a sample space, where each element is equally likely to occur. If $A$ and $B$ are independent events associated with $S,$ then the number of ordered pairs $\left(A, B\right)$ such that $1\le \left|B\right|<\left|A\right|,$ equals