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AP EAMCET · Chemistry · Chemical Bonding and Molecular Structure

Which of the following statements is correct about \(\mathrm{CO}_3^{2-}\) ?
A. The hybridisation of central atom is \(s p^3\).
B. Its resonance structure has one \(\mathrm{C}-\mathrm{O}\) single bond and two \(\mathrm{C}=\mathrm{O}\) double bonds.
C. The average formal charge on each carbon atom is 0.67 units.
D. All \(\mathrm{C}-\mathrm{O}\) bond lengths are equal.

  1. A A
  2. B A and C
  3. C B and D
  4. D C and D
Verified Solution

Answer & Solution

Correct Answer

(D) C and D

Step-by-step Solution

Detailed explanation

The hybridisation of central atom is \(s p^2\). Since a net charge of -2 is shared over 3 oxygen atoms, hence formal charge \(=0.67\) units. In resonating structures bonds are not fixed and therefore, all bond lengths are equal. Hence, options (c) and (d) are correct.